조정 메커니즘
협동 메커니즘에서 FLP는 H-H 결합이 동시에 끊어지는 방식으로 H2와 상호작용한다.전자가 풍부한 아민은 H2 분자에 전자를 공급하고, 전자가 부족한 붕탄은 전자를 받아 H-H 결합이 끊어지고 H2가 방출된다.이 메커니즘은 한 단계에서 발생하며 명확하게 정의되지 않은 중간체입니다.
화학 원료를 구입해야하는 경우 요청 정보를 제출하여최신견적을받으십시오.
조정 메커니즘의 학술 논문
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Heterolytic cleavage of dihydrogen by "frustrated lewis pairs" comprising bis(2,4,6-tris(trifluoromethyl)phenyl)borane and amines: Stepwise versus concerted mechanism
화학 물질
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bis[2,4,6-tris(trifluoromethyl)phenyl]borane
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4
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Stereospecific, R2AlCl-Promoted Intramolecular Ene Reaction of a 1,6-Dienoate: Evidence for a Concerted Mechanism
화학 물질
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2,2-Pyrrolidinedicarboxylic acid, 3-(2-ethoxy-2-oxoethyl)-4-(1-methylethenyl)-1-(trifluoroacetyl)-, diethyl ester, trans-
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Intermolecular C-H amination of complex molecules: Insights into the factors governing the selectivity
화학 물질
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(1S,6R)-N-[N-(S)-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-3-methyl-6-(prop-1-en-2-yl)cyclohex-2-enamine
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Competing base-promoted E2 and E1 reactions of an acidic tertiary substrate
화학 물질
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4-chloro-4-(4'-nitrophenyl)pentan-2-one
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Fast and highly chemoselective alkynylation of thiols with hypervalent iodine reagents enabled through a low energy barrier concerted mechanism
화학 물질
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1-[2,4,6-trimethylphenylethynyl]-1,2-benziodoxol-3(1H)-one
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Evidence for 2-Hexene-1,6-diyl Diradicals Accompanying the Concerted Diels-Alder Cycloaddition of Acrylonitrile with Nonpolar 1,3-Dienes
화학 물질
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1-Methylene-2-(acetoxymethyl)cyclohexane
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Elimination Reactions of Hydrazonium Salts: Experimental and Theoretical Evidence for a Large Stereoelectronic Effect of Nitrogen
화학 물질
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benzaldehyde N,N-dimethyl-N-(p-bromobenzyl)hydrazonium bromide
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A "frustrated" cope rearrangement: Thermal interconversion of 2,6-diphenylhepta-1,6-diene and 1,5-diphenylbicyclo[3.2.0]heptane
화학 물질
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2,5-diphenylhexa-1,5-diene-1,6-13C2
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Ramberg-Backlund rearrangement vs. β-Elimination of haloform from trichloro and trifluoromethyl sulfones
화학 물질
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Diphenylmethyl-dichlormethyl-sulfon
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Reactions of a platinum(II) agostic complex: Decyclometalation, dicyclometalation, and solvent-switchable formation of a rollover complex
화학 물질
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[(2-tert-butyl-6-(4-fluorophenyl)pyridine(-2H))Pt(PPh3)]
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Intramolecular Diels-Alder Reactions of 3H-Pyrroles Resulting from the Thermal Rearrangements of 2H-Pyrroles
화학 물질
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10,10-dimethyl-7,9-diphenyl-8-azatricyclo<5.2.1.01,5>dec-8-ene
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Intermolecular cyclopropanation versus CH insertion in Rh(II)-catalyzed carbenoid reactions
화학 물질
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2,6-di-tert-butyl-4-methylphenyl (cyclohexen-3-yl)acetate
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Unprecedented synthesis of 3-alkenyl-3-ethoxy-2-iminoketones via 1,3-dipolar cycloadditions of nitrones with alkynyl Fischer carbene complexes
화학 물질
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(2Z,3Z)-3-ethoxy-1,4-diphenyl-2-(phenylimino)but-3-en-1-one
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STEREOSELECTIVE KETENE-CLAISEN REARRANGEMENT OF CHIRAL ALLYLTHIOETHERS
화학 물질
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(S)-3-Isopropylsulfanyl-cyclohexene
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Cycloaddition Routes to Tricyclo<5.4.01,7.02,9>undecanes: A Direct Total Synthesis of (+)-Longifolene via an Intramolecular Diels-Alder Strategy
화학 물질
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Spiro[2.4]hepta-4,6-diene-1-carboxaldehyde, 2,2-dimethyl-, (R)- (9CI)
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Intermolecular (4+3) cycloadditions of aziridinyl enolsilanes
화학 물질
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N-methoxy-N-methyl-(S)-1-triphenylmethyl-aziridine-2-carboxamide
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