버아민
버아민(RNH2)은 중아민보다 친핵성이 있는데, 이는 질소에 수소 원자를 하나 추가해 더 나은 친핵제로 만들기 때문이다. 에틸로니트릴에서 버아민은 다양한 친전 시약과 친핵 대체 반응을 보일 수 있습니다.예를 들어, 알킬할로겐화합물과 반응하여 중아민을 생성하거나, 이미드할로겐화물과 반응하여 아미드를 생성할 수 있습니다. 에틸로니트릴에서 버아민의 반응 활성도는 공간위 차단의 영향도 받는다.크기가 작은 버아민에 비해 부피가 큰 버라민은 반응성을 저하시킬 수 있습니다.
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버아민의 학술 논문
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Nucleophilic reactivities of primary and secondary amines in acetonitrile
화학 물질
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[bis(4-dimethylaminophenyl)methyl]-(2,2,2-trifluoroethyl)amine
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7
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15
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Silica sulfuric acid-mediated synthesis of β-enaminones and β-enaminoesters under microwave irradiation
화학 물질
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9-bromo-4,4-dimethyl-2-(naphthalen-1-yl)-4,5-dihydropyrrolo[2,3,4-kl]acridin-1(2H)-one
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A convenient method for synthesis of optically active β-hydroxyamines from primary amines through enecarbamates as key intermediates
화학 물질
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Carbamic acid, (2-phenylethenyl)-, methyl ester, (Z)-
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Metal-free oxidative olefination of primary amines with benzylic C-H bonds through direct deamination and C-H bond activation
화학 물질
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(E)-2-(4-Chlorostyryl)quinoline
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One-pot three-component synthesis of 4(3 H)-quinazolinones from benzyl halides, isatoic anhydride, and primary amines
화학 물질
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2,3-di-(4-chlorophenyl)-quinazoline-4(3H)-one
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Hydrosiloxane-Ti(OiPr)4: An efficient system for the reduction of primary amides into primary amines as their hydrochloride salts
화학 물질
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N-(2-(trifluoromethyl)benzyl)-1-(2-(trifluoromethyl)phenyl)methanimine
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Chemoselective acylation of primary amines and amides with potassium acyltrifluoroborates under acidic conditions
화학 물질
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ethyl 4-(benzoylcarbamoyl)benzoate
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Highly selective enzymatic kinetic resolution of primary amines at 80°C: A comparative study of carboxylic acids and their ethyl esters as acyl donors
화학 물질
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Butanamide, N-(1-methyl-3-phenylpropyl)-, (S)-
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Zirconium-catalyzed intermolecular hydroamination of alkynes with primary amines
화학 물질
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N-(4-methylphenyl)-N-(1-phenylpropyl)amine
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Dimethyldioxirane Oxidation of Primary Amines
화학 물질
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Diazene, didecyl-, 1,2-dioxide
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Solvent-free kinetic resolution of primary amines catalyzed by Candida antarctica lipase B: Effect of immobilization and recycling stability
화학 물질
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2-methoxy-N-[1-(4-fluorophenyl)ethyl]acetamide
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Heterogeneously catalyzed self-condensation of primary amines to secondary amines by supported copper catalysts
화학 물질
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4-(trifluoromethyl)-N-[[4-(trifluoromethyl)phenyl]methyl]-benzenemethanamine
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Primary amines by transfer hydrogenative reductive amination of ketones by using cyclometalated IrIII catalysts
화학 물질
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1-(2,5-dimethylthien-3-yl)ethanamine
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An efficient and atom-economical route to: N -aryl amino alcohols from primary amines
화학 물질
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N-Phenyl-5-amino-2-pentanol
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