반응 메카니즘
이 반응은 보통 베타-아미노아크릴아마이드가 프탈레이트디이소프로필 에스테르에 의해 산화되면서 시작된다.이 산화 과정은 중간 화합물의 형성을 초래할 수 있다. 반응의 핵심 단계는 중간체의 분자 내 루프화를 다룬다.베타아미노와 아크릴아미드기단이 같은 분자 내에서 반응하여 이악산과 2H-질소잡환프로판 형성
화학 원료를 구입해야하는 경우 요청 정보를 제출하여최신견적을받으십시오.
반응 메카니즘의 학술 논문
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Oxidative Cyclization of β-Aminoacrylamides Mediated by PhIO: Chemoselective Synthesis of Isoxazoles and 2 H-Azirines
화학 물질
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N-(4-CHLOROPHENYL)-3,5-DIMETHYL-4-ISOXAZOLECARBOXAMIDE
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One-step synthesis of 1-halo-1,3-butadienes via ruthenium-catalysed hydrohalogenative dimerisation of alkynes
화학 물질
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(1Z,3E)-1-chloro-1,4-di(4-methoxyphenyl)buta-1,3-diene
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Low-temperature n-butyllithium-induced rearrangement of allyl 1,1-dichlorovinyl ethers
화학 물질
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((Z)-41-(2,2-dichlorovinyloxy)but-2-enyloxy)(tert-butyl)diphenylsilane
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Asymmetric synthesis of a β-lactam framework via the conjugate addition of amidocuprates(I) to chiral enoates
화학 물질
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(R,E)-3-benzylamino-5-phenyl-4-penten-1-ol
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Reactions involving Fluoride Ion. Part 23. Thermolytic Defluorination of Perfluoroalkenes in the Synthesis of Fluorinated Dienes and Cyclobutenes
화학 물질
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perfluoro-(3-methylbuta-1,2-diene)
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Electron-transfer substitution reactions: The p-nitrocumyl system
화학 물질
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Pyrrolidine, 1-[1-methyl-1-(4-nitrophenyl)ethyl]-
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Catalytic, enantioselective synthesis of α-aminonitriles with a novel zirconium catalyst
화학 물질
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()-2-amino-4-methylvaleramide
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Transition-metal-free tunable chemoselective nfunctionalization of indoles with ynamides
화학 물질
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ethynyl(phenyl)carbamic acid tert-butyl ester
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An efficient approach to fused indolines via a copper(I)-catalyzed reaction of sulfonyl azide with 2-ethynylaryl methylenecyclopropane
화학 물질
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7-methoxy-1-tosyl-2,3-dihydro-1H-benzo[f]indole
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Citric acid as a trifunctional organocatalyst for thiocyanation of aromatic and heteroaromatic compounds in aqueous media
화학 물질
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3-브로모-4-티오시아나토아닐린
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Ceric ammonium nitrate
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REDOX-DEMERCURATION OF PHENYLMERCURY 4-FLUOROTHIOPHENOXIDE BY TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
화학 물질
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trans-4-fluorophenylbis(triphenylphosphine)platinum thiophenoxide
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Stereochemical and regiochemical studies on the alkylation of pentane-2,4-dione through its Co(II) complex
화학 물질
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5-methylcyclohex-2-enyl chloride
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Copper-catalyzed synthesis of purine-fused polycyclics
화학 물질
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3-benzyl-3H-benzo[4,5]imidazo[2,1-i]purine
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Reaction of electron-deficient N-sulfinylanilines with chiral α-hydroxy acids: A new process for the synthesis of enantiomerically pure α-hydroxy amides
화학 물질
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Benzenamine, 2,4-dichloro-N-sulfinyl-
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Rates of decarboxylation of acyloxy radicals formed in the photocleavage of substituted 1-naphthylmethyl alkanoates
화학 물질
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Naphthalene, 1-(2,2-dimethylpropyl)-
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Homogeneous catalytic hydrosilylation of the C=C double bond with platinum catalysts
화학 물질
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methyl 2-methyl-3-triphenylsilylpropionate
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Reaction of Olefins with Malonic Acid Derivatives in the Presence of Manganese(III) Acetate
화학 물질
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2-bromo-4-phenyl-4-butanolide
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CuCl2-catalyzed highly stereoselective and chemoselective reduction of alkynyl amides into α,β-unsaturated amides using silanes as hydrogen donors
화학 물질
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2-Propynamide, N-methoxy-N-methyl-3-phenyl-
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Palladium-catalyzed oxidative cyclizations: Synthesis of dihydropyranones and furanones
화학 물질
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3(2H)-Furanone, 5-(4-methoxyphenyl)-2,2-dimethyl-
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Further studies on the cyclisation of 3-hydroxy-2'-nitrodiphenyl ethers and related compounds
화학 물질
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10H-Phenoxazin-3-aMine
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4
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염화 암모늄
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The vicinal functionalization of olefins: A facile route to the direct synthesis of β-chlorohydrins and β-chloroethers
화학 물질
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(RS:3RS)-2-chloro-3-methoxy-3-phenyl-propionic acid
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Conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds catalyzed by a cationic rhodium complex
화학 물질
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5-Decen-2-one, 4-phenyl-, (5E)-
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Intramolecular O-arylation of phenols with phenylboronic acids: Application to the synthesis of macrocyclic metalloproteinase inhibitors
화학 물질
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(2S,3R)-2-[3-(4-Benzyloxy-phenyl)-propyl]-3-[(S)-2-(4-iodo-phenyl)-1-methoxycarbonyl-ethylcarbamoyl]-5-methyl-hexanoic acid tert-butyl ester
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Modelling Radical-initiated DNA Cleavage by Vinyl Epoxides
화학 물질
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2-<2-(tert-butyldiphenylsiloxy)ethoxy>ethyl 2,3-epoxypent-4-enyl ether
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The coupling of arylboronic acids with nitroarenes catalyzed by rhodium
화학 물질
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C14H12O(18)O
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The novel reaction of ketones with o-oxazoline-substituted anilines
화학 물질
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2-(4,5-DIHYDRO-4,4-DIMETHYLOXAZOL-2-YL)벤제나민
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Lanthanum(III) nitrate hexahydrate or p-toluenesulfonic acid catalyzed one-pot synthesis of 4(3H)-quinazolinones under solvent-free conditions
화학 물질
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4(3H)-Quinazolinone, 3-(2-fluorophenyl)-
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Kinetic study of axial ligand substitution in (tetraphenylporphinato)chromium(III) chloride
화학 물질
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[Cr(5,10,15,20-tetraphenylporphinate)Cl(1-methylimidazole)]
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톨루엔
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Selective Base-Catalyzed Rearrangement of Epoxides into Ketones. Application to γ-Keto Sulfide Synthesis
화학 물질
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cis-2-((phenylthio)methyl)-5-methylcyclohexanone
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KINETICS OF THE N OXIDATION OF SOME COMPOUNDS OF THE PYRIDINE SERIES WITH PERBENZOIC ACID IN CHLOROFORM AND AQUEOUS DIOXANE
화학 물질
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Oxirane, 2-(4-chlorophenyl)-3-phenyl-, (2S,3S)-
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Trapping the oxyallyl cation intermediate derived from the Nazarov cyclization of allenyl vinyl ketones with nitrogen heterocycles
화학 물질
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tert-butyl 2-((2-methyl-3-oxo-5-phenylcyclopent-1-enyl)methyl)-1H-pyrrole-1-carboxylate
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Cobalt-Catalyzed Photochemical Carbonylation of Allylic Amines
화학 물질
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(E)-Pent-3-enoic acid ((E)-but-2-enyl)amide
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Studies on the bisoxazoline- and (-)-sparteine-mediated enantioselective addition of organolithium reagents to imines
화학 물질
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Benzenemethanamine, a-butyl-, (R)-
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Hydrazidohydroxylation of styrenes with N-acetylaminophthalimide using phenyliodine(III) bis(trifluoroacetate) (PIFA)
화학 물질
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1-(4-chlorophenyl)-2-[N-(1,3-dioxoisoindolin-2-yl)acetamido]ethyl 2,2,2-trifluoroacetate
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Nickel-catalyzed allylic substitution of simple alkenes
화학 물질
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(E)-1-methoxy-4-(penta-1,4-diene-1-yl)benzene
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REDUCTIVE PINACOL-TYPE REARRANGEMENT OF GHIRAL α-MESYLOXY KETONES PROMOTED BY ORGANOALUMINIUM COMPOUNDS
화학 물질
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1-Propanone, 2-(1-ethoxyethoxy)-1-phenyl-
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Structural effects on interconversion of oxygen-substituted bisketenes and cyclobutenediones
화학 물질
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3-Cyclobutene-1,2-dione, 3,4-bis(4-nitrophenoxy)-
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Rhodium(II)-Catalyzed Formal [3 + 2] Cycloaddition of N-Sulfonyl-1,2,3-triazoles with Isoxazoles: Entry to Polysubstituted 3-Aminopyrroles
화학 물질
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5-butyl-3-(4-chlorophenyl)isoxazole
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Reactions of N- or N'-Blocked N-acylureas with Amines
화학 물질
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포르마닐라이드
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Gold(i)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination
화학 물질
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4-(cyclohexylmethyl)-4-vinyl-1,2,3-oxathiazinane 2,2-dioxide
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Metal-Free Electrophilic Alkynylation of Sulfenate Anions with Ethynylbenziodoxolone Reagents
화학 물질
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1-methyl-4-[(2-nitroethyl)sulfanyl]benzene
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Conjugate Addition of Diboron Catalyzed by O -Monoacyltartaric Acids
화학 물질
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(S)-3-hydroxy-1-(4’-methoxylphenyl)-3-phenylpropan-1-one
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Bis(phosphinite) with C2-symmetric axis; Effects on the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of acetophenone derivatives
화학 물질
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(2S)-2-[benzyl(2-{benzyl[(1S)-2-hydroxy-1-phenylethyl]amino}ethyl)amino]-2-phenylethan-1-ol
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Conversion of bromoalkenes into alkynes by wet tetra-n-butylammonium fluoride
화학 물질
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4-bromo-5-phenylpent-4-en-1-ol
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Indirect electrochemical oxidation of cyclic ketones: Influence of ring size, mediator and supporting electrolyte on the result of the reaction
화학 물질
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1-Cycloundecene-1-carboxylic acid, methyl ester, (E)-
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