친핵 공격
친핵산소원(대개 알코올, 아민 또는 기타 산소 함유 화합물)은 활성화되는 카르복실 탄소 원자를 공격하여 금속-올염 중간체의 형성을 초래할 수 있다.
화학 원료를 구입해야하는 경우 요청 정보를 제출하여최신견적을받으십시오.
친핵 공격의 학술 논문
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Alkaline earth catalysis of alkynyl alcohol hydroalkoxylation/cyclization
화학 물질
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(2E)-2-ethylidenetetrahydrofuran
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Inner- and Outer-Sphere Roles of Ruthenium Phosphido Complexes in the Hydrophosphination of Alkenes
화학 물질
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[Ru(η5-indenyl)(κ2-(o-C6H4)PPh2)(PPh2H)]
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FeCl3 as Lewis acid catalyzed one-pot three-component aza-Friedel-Crafts reactions of indoles, aldehydes, and tertiary aromatic amines
화학 물질
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N,N-dimethyl-4-((1-methyl-1H-indol-3-yl)(p-tolyl)methyl)aniline
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Asymmetric electrophilic amination of chiral phosphorus-stabilized anions
화학 물질
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6,6-dimethyl-N-<(S)-(1)-phenylethyl>-2-oxo-1,3,2-oxazaphosphorinane
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Palladium-Catalyzed Oxidative Synthesis of α-Acetoxylated Enones from Alkynes
화학 물질
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3-oxo-3-phenylprop-1-en-2-yl acetate
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Copper(I)-picolinic acid catalyzed N-arylation of hydrazides
화학 물질
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tert-butyl 1-(4-fluorophenyl)hydrazinecarboxylate
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Selective Base-Catalyzed Rearrangement of Epoxides into Ketones. Application to γ-Keto Sulfide Synthesis
화학 물질
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cis-2-((phenylthio)methyl)-5-methylcyclohexanone
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An efficient synthesis of 4-heterofunction-substituted 3-(1-hydroxy)ethylazetidin-2-ones from 3-(1-hydroxy)ethyl-4-phenylsulfinylazetidin-2-one by reaction with silylated heteronucleophiles
화학 물질
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(3S,4R)-4-benzoylthio-3-<(1R)-(1-tert-butyldimethylsiloxy)ethyl>-azetidin-2-one
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Aminoalkylation with aldehydes mediated by solid lithium perchlorate
화학 물질
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1-(1-phenylpropyl)pyrrolidine
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Reaction of Acyl Chlorides with in Situ Formed Zinc Selenolates: Synthesis of Selenoesters versus Ring-Opening Reaction of Tetrahydrofuran
화학 물질
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Se-phenyl 2-bromobenzeneselenoate
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Unexpected resistance to base-catalyzed hydrolysis of nitrogen pyramidal amides based on the 7-azabicyclic[2.2.1]heptane scaffold
화학 물질
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7-Azabicyclo[2.2.1]heptane, 7-benzoyl-
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Mechanistic Aspects of the Silver(I)-Promoted Rearrangement of Cyclopropene Derivatives
화학 물질
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1H-Indene, 2,3-diphenyl-1-(phenylmethyl)-
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Nucleophilic attack on 2,1-benzisothiazolium salts
화학 물질
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1-methyl-2,1-benzisothiazole<2,3-b>-5-phenyl-1,2-dithiole
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Action of Alkali on O-Benzylated Aldoses: A Simple Rationalization of Some Reactions Occurring in Alkaline Media
화학 물질
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(2E,4Z,6S)-4,7-bis(benzyloxy)-6-hydroxyhepta-2,4-dienenitrile
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Acid-catalyzed reactions of epoxides for atmospheric nanoparticle growth
화학 물질
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2-methylbut-3-ene-1,2-diol
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Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides
화학 물질
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(benzyl)(4-bromophenyl)(imino)-λ6-sulfanone
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Molecular iodine-catalyzed C3-alkylation of 4-hydroxycoumarins with secondary benzyl alcohols
화학 물질
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3-(1,3-diphenylprop-2-ynyl)-6-ethoxy-4-hydroxy-2H-chromen-2-one
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Catalytic generation of activated carboxylates: Direct, stereoselective synthesis β-hydroxyesters from epoxyaldehydes
화학 물질
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(2S,3S)-2-Methyl-3-phenyl-oxirane-2-carbaldehyde
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N-alkylation of N-arylsulfonyl-α-amino acid methyl esters by trialkyloxonium tetrafluoroborates
화학 물질
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(S)-methyl 2-(4-methoxyphenylsulfonamido)propanoate
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Intramolecular Oxidative Cyclization Reactions of Trivalent Phosphorus and Carbonyl Functions
화학 물질
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Benzoic acid, 2,2'-[(phenylphosphinidene)bis(oxy)]bis-, dimethyl ester
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Iodine-catalyzed efficient hydrophosphonylation of N-tosyl aldimines
화학 물질
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Phosphonic acid, [(4-chlorophenyl)[[(4-methylphenyl)sulfonyl]amino]methyl]-, diethyl ester
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Experimental and theoretical investigations into the stability of cyclic aminals
화학 물질
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[2-(Isopropylamino-methyl)-phenyl]-methyl-amine
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Gold catalysis: benzanellation versus alkylidenecyclopentenone synthesis
화학 물질
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2-(5-methylfuran-2-yl)-1-phenylethan-1-one
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Subtle electronic effects in metal-free rearrangement of allenic alcohols
화학 물질
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C14H12ClF3O5S
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A novel cephalosporin dehydrothiazine ring cleavage mode
화학 물질
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4-[1-Dimethylamino-meth-(Z)-ylidene]-3-methyl-5,5,8-trioxo-7-(2-phenoxy-acetylamino)-5λ6-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid allyl ester
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Unusual rearrangements of 2-aroylimidoyl-2-phenylethylidene to 2,5- disubstituted oxazoles
화학 물질
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ethyl benzoyl-(3-13C) acetate
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Ramberg-Backlund rearrangement vs. β-Elimination of haloform from trichloro and trifluoromethyl sulfones
화학 물질
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Diphenylmethyl-dichlormethyl-sulfon
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BRIDGEHEAD NITROGEN HETEROCYCLES FROM 2,4,6-TRIPHENYLPYRYLIUM CATION AND THIOSEMICARBAZIDE OR THIOCARBOHYDRAZIDE
화학 물질
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Pyrazolo[1,5-c]pyrimidine-7(3H)-thione, 3a,6-dihydro-2,3a,5-triphenyl-
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Addition of Twisted 1-Thioacetyl-2,2-diaminoethylenes to Dimethyl Acetylenedicarboxylate. Formation and Ring Opening of Thiopyran-4-spiro-2'-(1',3'-diazacyclanes)
화학 물질
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1,3-Cyclohexanedithione, 5,5-dimethyl-2-[tetrahydro-1,3-bis(phenylmethyl)-2(1H)-pyrimidinylidene ]-
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PARTICIPATION D'UN GROUPE AMIDE A LA FORMATION DE SELS DE DIOXOLANNE-1,3 YLIUM-2; MODELE BIOMIMETIQUE DE REACTION DE PEPTIDATION
화학 물질
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trans-2-acetoxycyclopentanol
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Pd-Catalyzed Carbonylation of Acyl Azides
화학 물질
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Benzamide, N-[[(2-methylphenyl)amino]carbonyl]-
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STEREOSELECTIVE CYCLIZATION OF (E)- AND (Z)-5,6-DIMETHYL-8-TRIMETHYLSILYL-6-OCTENALS
화학 물질
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(1S,2R,3S)-2,3-Dimethyl-2-vinyl-cyclohexanol
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N,N-Dimethylformamide (DMF) as a Source of Oxygen to Access α-Hydroxy Arones via the α-Hydroxylation of Arones
화학 물질
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1-Propanone, 2-hydroxy-1-(4-methoxyphenyl)-
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Dual Regioselectivity in the Photoallylation of Electron-Deficient Alkenes by Allylic Silanes
화학 물질
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2-(1-p-tolylbut-3-enyl)malononitrile
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ARENE-CHROMIUM-TRICARBONYL COMPLEXES: STEREOSELECTIVE REACTIONS WITH ISOCYANIDE
화학 물질
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(4S,5S)-4-(Toluene-4-sulfonyl)-5-o-tolyl-4,5-dihydro-oxazole
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