촉매 순환
게르마늄 촉매는 FU-PHOS 배위와 손성락합물을 형성한다. 엔프로필 기저물은 게르마늄 촉매에 결합되어 있다. 친핵 시약은 엔프로필카본을 공격해 이탈기단을 대체한다. Fu-Phos 리간드에 의해 제공되는 손성환경에 의해 친핵분자가 높은 대영체 선택성을 갖는 엔프로필렌 탄소를 공격하도록 유도하여 수성 생성물의 형성을 초래한다.
화학 원료를 구입해야하는 경우 요청 정보를 제출하여최신견적을받으십시오.
촉매 순환의 학술 논문
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Palladium-catalyzed enantioselective allylic substitution in the presence of monodentate furanoside phosphoramidites
화학 물질
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dimethyl (1R,2E)-(1-phenylbut-2-en-1-yl)malonate
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Fe3O4@SiO2/Schiff base/Pd complex as an efficient heterogeneous and recyclable nanocatalyst for chemoselective: N -arylation of O -alkyl primary carbamates
화학 물질
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Cyclohexanol, 5-methyl-2-(1-methylethyl)-, phenylcarbamate
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Synthesis of E-Alkyl Alkenes from Terminal Alkynes via Ni-Catalyzed Cross-Coupling of Alkyl Halides with B-Alkenyl-9-borabicyclo[3.3.1]nonanes
화학 물질
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(E)-hex-1-ene-1,6-diyldibenzene
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Multicomponent Catalytic Asymmetric Synthesis of trans-Aziridines
화학 물질
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N-benzylidene-bis(4-methoxy-3,5-di-tert-butylphenyl)methylamine
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Mechanistic Studies on the Anodic Functionalization of Alkenes Catalyzed by Diselenides
화학 물질
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bis[2-(tert-butylsulfonyl)phenyl] diselenide
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Insight into the mechanism of the asymmetric ring-opening aminolysis of 4,4-dimethyl-3,5,8-trioxabicyclo[5.1.0]octane catalyzed by titanium/BINOLate/ water system: Evidence for the Ti(BINOLate)2-bearing active catalyst entities and the role of water
화학 물질
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(5S,6R)-6-(N-benzylacetamido)-2,2-dimethyl-1,3-dioxepan-5-yl acetate.
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A new methodology for synthesis of a chiral phosphinocarboxylic acid through michael cyclization-aldol tandem reaction of chiral α,β,χ,ψ-unsaturated bisphosphine oxide and application in palladium-catalyzed asymmetric allylic alkylation
화학 물질
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2-(diphenylphosphonoyl)-2-[(1S,2S,3S,5S)-5-(diphenylphosphonoyl)-2,3-dimethoxycyclopentyl]-1-phenylethanol
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STEREOSELCTION IN THE MICHAEL ADDITION REACTION. 1. THE MOKAIYAMA-MICHAEL REACTION
화학 물질
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(2S,3R)-2,6,6-Trimethyl-5-oxo-3-phenyl-heptanoic acid tert-butyl ester
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A nonenzymatic acid/peracid catalytic cycle for the Baeyer-Villiger oxidation
화학 물질
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4-butyl-4-hydroxycyclohexanon
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Palladium-catalyzed formylation of aryl bromides: Elucidation of the catalytic cycle of an industrially applied coupling reaction
화학 물질
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Pd2Br2(P(C4H9)(C(CH3)3)2)2(COC6H4CF3)2
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Osmium-catalyzed olefin dihydroxylation and aminohydroxylation in the second catalytic cycle
화학 물질
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ethyl (2R,3S)-3-(2,4-dinitrophenyl)-2-hydroxy-3-(4-methylphenylsulfonamido)propanoate
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Enantioselective allylations of azlactones with unsymmetrical acyclic allyl esters
화학 물질
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4-methyl-4-(3-methyl-2-butenyl)-2-phenyl-2-oxazolin-5-one
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Synthesis of tetrasubstituted cyclopentadienes via palladium-catalyzed reaction of (Z)-2-En-4-yn acetates and N-methyl indoles
화학 물질
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1-methyl-3-(2,4,5-triphenyl-cyclopenta-1,4-dienyl)-1H-indole
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Re-entry of tin in N-alkylation: First example of a homogeneous heterobimetallic Pd-Sn catalyst for base and additive free alkylation of amine and surrogates with alcohol
화학 물질
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Palladium, chloro(trichlorostannyl)bis(triphenylphosphine)-
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Ultrasound promoted Barbier reactions and Csp3-Csp2 Stille coupling for the synthesis of diarylmethanes and substituted benzophenones
화학 물질
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3-(3,5-dimethoxybenzoyl)benzoic acid
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A surface-confined O=MnV(salen) oxene catalyst and high turnover values in asymmetric epoxidation of unfunctionalized olefins
화학 물질
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Benzaldehyde, 2-(1,1-dimethylethyl)-3-hydroxy-
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Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: Synthesis of six-membered N-heterocycles
화학 물질
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N-(4-methylphenyl)sulfonyl-2-(2(Z)-buten-1-yloxy)ethylamine
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Reactions of a platinum(II) agostic complex: Decyclometalation, dicyclometalation, and solvent-switchable formation of a rollover complex
화학 물질
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[(2-tert-butyl-6-(4-fluorophenyl)pyridine(-2H))Pt(PPh3)]
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Divergent Iron-Catalyzed Coupling of O-Acyloximes with Silyl Enol Ethers
화학 물질
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(E)-1-phenylpropan-1-one O-acetyl oxime
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Sequential Palladium-Catalyzed Allylic Alkylation/retro-Dieckmann Fragmentation Strategy for the Synthesis of α-Substituted Acrylonitriles
화학 물질
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(E)-3-(m-tolyl)allyl acetate
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Geminal bis(sulfoximine)s: Synthesis and applications in asymmetric catalysis
화학 물질
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(+)-(S)-allyl-p-toluenesulphinamide
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REGIOSELECTIVE SYNTHESIS OF DIHYDROFURANS FROM 2,2-DIBROMO-1,3-DIKETONE AND OLEFIN USING COPPER
화학 물질
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4(2H)-Benzofuranone, 3,5,6,7-tetrahydro-2,6,6-trimethyl-2-phenyl-
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Intermolecular cyclopropanation versus CH insertion in Rh(II)-catalyzed carbenoid reactions
화학 물질
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2,6-di-tert-butyl-4-methylphenyl (cyclohexen-3-yl)acetate
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Diphenylprolinol silyl ether as catalyst of an asymmetric, catalytic, and direct Michael reaction of nitroalkanes with α,β-unsaturated aldehydes
화학 물질
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(S)-3-(4-chlorophenyl)-4-nitrobutyraldehyde
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A direct amine-palladium acetate cocatalyzed saegusa oxidation reaction of unmodified aldehydes to α,β-unsaturated aldehydes
화학 물질
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2-Propenal, 3-(4-acetylphenyl)-
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Enantioselective copper-catalyzed conjugate addition of trimethylaluminium to β,γ-unsaturated α-ketoesters
화학 물질
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ethyl 2-oxo-4-(4-bromophenyl)-3-buten-1-oate
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Pd/PTABS: Catalyst for Room Temperature Amination of Heteroarenes
화학 물질
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2-chloro-4-(4-tosylpiperazin-1-yl)pyrimidine
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Palladium-Catalyzed Intermolecular Vinylation of Cyclic Alkenes
화학 물질
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(Z)-1-(3-cyclohexenyl)-1-hexene
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Nickel-catalyzed reductive alkylation of halogenated pyridines with secondary alkyl bromides
화학 물질
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2-(1-tosylpiperidin-4-yl)pyridine
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A broadly applicable strategy for entry into homogeneous nickel(0) catalysts from air-stable nickel(II) complexes
화학 물질
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trans-bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride
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Asymmetric catalyzed allylic substitution using a Pd/P-S catalyst library with exceptional high substrate and nucleophile versatility: DFT and Pd-π-allyl key intermediates studies
화학 물질
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2,4-Pentanedione, 3-[(1S)-1,3-diphenyl-2-propenyl]-
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Ageneral strategy for organocatalytic activation of c-h bonds via photoredox catalysis: Direct arylation of benzylic ethers화학 물질
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4-(isochroman-1-yl)benzonitrile
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Iodine-promoted 2-arylsulfanylphenol formation using cyclohexanones as phenol source
화학 물질
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4-((2-hydroxyphenyl)thio)benzonitrile
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Grubbs catalysts in intramolecular carbene C(sp3)-H insertion reactions from α-diazoesters
화학 물질
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Ethanol, 2-[(1-methylethyl)(phenylmethyl)amino]-
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Design and modular parallel synthesis of a MCR derived α-helix mimetic protein-protein interaction inhibitor scaffold
화학 물질
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5-[이소시아노-(톨루엔-4-술포닐)-메틸]-벤조[1,3]디옥솔
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ASYMMETRIC SYNTHESES VIA METALATED CHIRAL HYDRAZONESOVERALL ENANTIOSELECTIVE α-ALKYLATION OF ACYCLIC KETONES
화학 물질
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(+)-2-methoxymethyl-1-(2-methyl-1-n-butyl-pentylideneamino)-pyrrolidine
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Chiral helical oligotriazoles: New class of anion-binding catalysts for the asymmetric dearomatization of electron-deficient N -heteroarenes
화학 물질
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3-[(TriMethylsilyl)ethynyl]aniline
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Chiral amine-imine ligands based on trans-2,5-disubstituted pyrrolidines and their application in the palladium-catalyzed allylic alkylation
화학 물질
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(+)-2-[2-[(2R,5R)-2,5-diphenylpyrrolidin-1-yl]ethyl]pyridine
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Nickel-catalyzed heteroannulation of o-haloanilines with alkynes
화학 물질
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3-phenyl-2-(trimethylsilyl)-1H-indole
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B(C6F5)3-Catalyzed (Convergent) Disproportionation Reaction of Indoles
화학 물질
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dimethyl-1,7 indoline
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Electron-deficient pyridinium salts/thiourea cooperative catalyzed O-glycosylation via activation of O-glycosyl trichloroacetimidate donors
화학 물질
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p-methoxybenzyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside
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Pd-catalyzed Heck-type cascade reactions with N-tosyl hydrazones: An efficient way to alkenes via in situ generated alkylpalladium
화학 물질
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(E)-1,3-dimethyl-3-styrylindolin-2-one
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