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히드록시알데히드 반응
히드록시알데히드 반응은 베타-히드록시알데히드나 케톤을 생성하는 고전적인 방법이다.알데히드 또는 케톤은 알칼리 존재 하에서 자체 반응과 함께 히드록시알데히드를 생성한 후 탈수하여 알렌알데히드(엔올에테르)를 얻거나 추가반응을 통해 올레민을 생성한다.
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히드록시알데히드 반응의 학술 논문
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A NOVEL ROUTE TO ALDEHYDIC ENOL ETHERS AND ENAMINES
화학 물질
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<(Diethylamino)methylene>cyclohexane
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Gold-catalyzed hydrosilyloxylation driving tandem aldol and Mannich reactions
화학 물질
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[2-(hex-1-ynyl)phenyl]diphenylsilane
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Domino multicomponent michael - Michael - Aldol reactions under phase-transfer catalysis: Diastereoselective synthesis of pentasubstituted cyclohexanes
화학 물질
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2,4-Pentadien-1-one, 1-(4-chlorophenyl)-5-phenyl-, (E,E)-
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Crossed aldol reaction using cross-linked polymer-bound lithium dialkylamide
화학 물질
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2',6'-bis(1,1-dimethylethyl)-4'-methylphenyl (2SR,3RS)-2-methyl-3-hydroxybenzenepropanoate
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Asymmetric aldol reaction catalyzed by the anion of an ionic liquid
화학 물질
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1-butyl-3-methylimidazolium (3R,5S)-5-(methoxycarbonyl)-pyrrolidin-3-yl sulfate
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Ruthenium-catalyzed tandem olefin migration/aldol and Mannich-type reactions in water and protic solvents
화학 물질
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3-Hydroxy-2-methyl-3-naphthalen-2-yl-1-phenyl-propan-1-one
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Highly Enantioselective Aldol Reaction: Development of a New Chiral Auxiliary from cis-1-Amino-2-hydroxyindan
화학 물질
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(3aS,8aR)-3-((E)-(2S,3R)-3-Hydroxy-2-methyl-5-phenyl-pent-4-enoyl)-3,3a,8,8a-tetrahydro-indeno[1,2-d]oxazol-2-one
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C2-symmetric bisprolinamide as a highly efficient catalyst for direct aldol reaction
화학 물질
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N,N'-bis[(S)-N-benzyloxycarbonylprolyl]-1,2-ethylenediamine
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A tandem Aldol-Grob reaction of ketones with aromatic aldehydes
화학 물질
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Benzene, 1-(1-butenyl)-3-chloro-, (Z)-
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STEREOSELECTIVE ALDOL REACTIONS USING TiCl4 AS STEREOCHEMICAL TEMPLATE
화학 물질
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(S)-3,3-Dimethoxy-2-methyl-propionic acid (1R,2S)-2-dimethylamino-1-phenyl-propyl ester
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Formation of dihydronaphthalenes via organocatalytic enatioselective michael-aldol cascade reactions with arylalkanes
화학 물질
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3-(2-chlorophenyl)-5,7-dinitro-3,4-dihydronaphthalene-2-carbaldehyde
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3-Methyl-2-cyclopentenone-Derived Synthons
화학 물질
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3-methyl-3-((4-methylphenyl)sulfonyl)cyclopentanone
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Asymmetrie direct vinylogous aldol reaction of furanone derivatives catalyzed by an axially chiral guanidine base
화학 물질
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(R)-3-bromo-5-((R)-hydroxy(phenyl)methyl)furan-2(5H)-one
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Exclusive α-coupling in the aldol reaction of unsaturated trimethylsilyl esters: An efficient and practical direct synthesis of unsaturated β-hydroxy acids
화학 물질
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Cyclohexaneacetic acid, a-ethenyl-1-hydroxy-
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N-(heteroarenesulfonyl)prolinamides-catalyzed aldol reaction between acetone and aryl trihalomethyl ketones
화학 물질
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(S)-5,5,5-trifluoro-4-hydroxy-4-(4-methoxyphenyl)pentan-2-one
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Regiospecific organocatalytic asymmetric aldol reaction of methyl ketones and α,β-unsaturated trifluoromethyl ketones
화학 물질
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(E)-1,1,1-trifluoro-7-phenylhept-3-en-2-one
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STANNOUS TRIFLATE: A NEW ALDOL REACTION VIA DIVALENT TIN ENOLATES
화학 물질
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(1SR,2SR)-1-hydroxy-2,4-dimethyl-1-phenylpentan-3-one
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4-Isopropyl-2-oxazolin-5-one anion as a new convenient formyl anion equivalent for conjugate addition and aldol reactions
화학 물질
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L-erythro-4-deoxy-pentose
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Synthesis of optically active 4-substituted 2-aminobutyrolactones and homoserines by combined aldol/photocyclization reactions of chromium aminocarbene complexes
화학 물질
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2(R)-(1-aza-2,2-dimethyl-3-oxa-5(S)-phenylcyclopent-1-yl)-4(R)-tert-butyl-1-oxotetrahydrofuran
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ENANTIOSELECTIVE SYNTHESIS OF β-HYDROXY-α-METHYL CARBONYL COMPOUNDS BY ALDOL REACTION
화학 물질
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Benzenemethanamine, a-[(1,1-dimethylethoxy)methyl]-N-(1-methylethyl)-, (R)-
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Diarylprolinol in the direct asymmetric aldol reaction of trifluoromethylacetaldehyde ethyl hemiacetal with aldehyde
화학 물질
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(4R,5R,E)-ethyl 4-benzyl-6,6,6-trifluoro-5-hydroxy-2-enoate
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Diastereo-face selectivity in the aldol reaction of boryl enolate derived from Oppolzer's sultam
화학 물질
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(2S,3S)-2-methyl-4-phenylbutane-1,3-diol diacetate
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Design and preparation of a novel prolinamide-based organocatalyst for the solvent-free asymmetric aldol reaction
화학 물질
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4-iodomethyl-2,2-dimethyl-[1,3]dioxolane
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Further observations on the rhodium (I)-catalysed tandem hydrosilylation-intramolecular aldol reaction
화학 물질
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2,6-Heptadienoic acid, 3-methyl-, methyl ester, (E)-
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New organocatalysts derived from tartaric and glyceric acids for direct aldol reactions
화학 물질
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(2S,3S,5R,6R)-3-(tert-butyldimethylsilyloxymethyl)-2-(p-toluenesulfonyloxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane
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Aldol Reactions with α-Trimethylsilyl Ketones. Dual Roles of the Trimethylsilyl Group for Regiospecific Generation of Enolate Equivalents
화학 물질
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2-Butanone, 4-hydroxy-4-phenyl-3-(phenylmethyl)-
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